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Effects of impregnation combined heat treatment on the pyrolysis behavior of poplar wood.

Identifieur interne : 000442 ( Main/Exploration ); précédent : 000441; suivant : 000443

Effects of impregnation combined heat treatment on the pyrolysis behavior of poplar wood.

Auteurs : Meihui Wu [République populaire de Chine] ; Juwan Jin [République populaire de Chine] ; Chengyang Cai [Finlande] ; Jingbo Shi [République populaire de Chine] ; Xuefeng Xing [République populaire de Chine] ; Jiabin Cai [République populaire de Chine]

Source :

RBID : pubmed:32182254

Descripteurs français

English descriptors

Abstract

To investigate the effects of urea-formaldehyde (UF) resin impregnation combined heat treatment (IMPG-HT) on the pyrolysis behavior of poplar wood, the chemical composition, pyrolysis characteristics, pyrolysis kinetics, and gaseous products released during pyrolysis of untreated (control), IMPG-HT, IMPG and HT woods were analyzed. The results demonstrate that IMPG-HT changes pyrolysis behavior of poplar wood significantly. Unlike the control and HT samples, the thermogravimetric / derivative thermogravimetric (TG/DTG) curves of IMPG wood shift toward lower temperature, and the shoulder on DTG curves weaken or even disappear. The maximum mass loss rate of IMPG-HT samples decreases, and carbon residual yield increases to 23% or more and activation energy (E) increases sharply after conversion rate (α) reaching 0.80. HT improves the thermal stability of IMPG wood, which is represented by the increase of decomposition temperature (Td) and DTG peak temperature (Tpeak) and the higher E value of IMPG-HT wood. For the pyrolysis gaseous products, IMPG-HT wood produces nitrogen-containing gases (HNCO and NH3) due to the presence of UF resin, but the amounts of these gases are less than that produced by IMPG wood because the heat treatment had removed part of N elements.

DOI: 10.1371/journal.pone.0229907
PubMed: 32182254
PubMed Central: PMC7077805


Affiliations:


Links toward previous steps (curation, corpus...)


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<div type="abstract" xml:lang="en">To investigate the effects of urea-formaldehyde (UF) resin impregnation combined heat treatment (IMPG-HT) on the pyrolysis behavior of poplar wood, the chemical composition, pyrolysis characteristics, pyrolysis kinetics, and gaseous products released during pyrolysis of untreated (control), IMPG-HT, IMPG and HT woods were analyzed. The results demonstrate that IMPG-HT changes pyrolysis behavior of poplar wood significantly. Unlike the control and HT samples, the thermogravimetric / derivative thermogravimetric (TG/DTG) curves of IMPG wood shift toward lower temperature, and the shoulder on DTG curves weaken or even disappear. The maximum mass loss rate of IMPG-HT samples decreases, and carbon residual yield increases to 23% or more and activation energy (E) increases sharply after conversion rate (α) reaching 0.80. HT improves the thermal stability of IMPG wood, which is represented by the increase of decomposition temperature (Td) and DTG peak temperature (Tpeak) and the higher E value of IMPG-HT wood. For the pyrolysis gaseous products, IMPG-HT wood produces nitrogen-containing gases (HNCO and NH3) due to the presence of UF resin, but the amounts of these gases are less than that produced by IMPG wood because the heat treatment had removed part of N elements.</div>
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   |wiki=    Bois
   |area=    PoplarV1
   |flux=    Main
   |étape=   Exploration
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   |texte=   Effects of impregnation combined heat treatment on the pyrolysis behavior of poplar wood.
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